ASTM D7493-08


Standard Test Method for Online Measurement of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatograph and Electrochemical DetectionASTM International / 15-Dec-2008 / 7 pages

1.1 This test method is for on-line measurement of volatile sulfur-containing compounds in gaseous fuels by gas chromatography (GC) and electrochemical (EC) detection. The test method is applicable to hydrogen sulfide, C1-C4 mercaptans, sulfides and tetrahydrothiophene (THT). 1.1.1 Carbonyl sulfide (COS) is not covered in this test method. 1.1.2 The detection range for sulfur compounds is approximately from 0.1 to 100 PPMv or 0.1 to 100 mg/m³. The detection range may vary depending on the sample injection volume, chromatographic peak separation and the sensitivity of specific EC detector. 1.2 This test method describes a GC-EC method employing packed GC columns and a specific detector as an illustration for natural gas and other gaseous fuel containing mainly light hydrocarbons. Alternative GC columns, detector designs and instrument parameters may be used for the same analysis or for different types of gaseous fuel, provided that appropriate chromatographic separation and optimal detection of these compounds can be achieved. 1.3 This test method does not intend to identify and measure all individual sulfur species, and is mainly employed for monitoring natural sulfur and sulfur odorant compounds commonly found in fuel gases or employed as an odorous warning agent in fuel gases. 1.4 The test method is normally employed for repetitive on-line monitoring of sulfur components in fuel gases with a single sulfur standard. The test method may be employed for laboratory-quality measurement with more extensive calibration. (See Test Methods D 5504, D 5623, D 6228, D 6968, ISO 19739, ISO 6326-2, and GPA 2199. 1.5 The test method can be used for measurement of all listed sulfur compounds in air or other gases, provided that no compound, which can interfere with the GC separation and electrochemical detection, is present. 1.6 This test method is written in conjunction with Practices D 5287, D 7165 and D 7166. 1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Keywords: electrochemical detection; gas chromatography; odorants; on-line measurement; sulfur compounds; ICS Number Code 75.160.30 (Gaseous fuels)

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